The electrochemical anodic oxidation method was used to prepare thin films of titanium dioxide (TiO2) semiconductors (undoped and doped with Mn). These films were used to test the oxidation of methanol (CH3OH), the degree of which was quantified by measuring the current density produced as a function of an applied potential between 0.5 V and 5.0 V. The value of the potential to be applied in order to prevent fast electron-hole recombination was determined. The observed phenomenon is explained by considering the wave nature of the electron.
Published in | American Journal of Physical Chemistry (Volume 3, Issue 4) |
DOI | 10.11648/j.ajpc.20140304.11 |
Page(s) | 41-46 |
Creative Commons |
This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited. |
Copyright |
Copyright © The Author(s), 2014. Published by Science Publishing Group |
Anodic Oxidation, TiO2, Mn-Doped TiO2, Applied Bias, Tunnelling Process
[1] | B. Ekoko, S. Jianian, S. XianRong, Thin Solid Films. 515 (2007) 5287-5397. |
[2] | D.M. Blake, Bibliography of work on the heterogeneous photocatalytic removal of hazardous compounds from water and air, in : National Technical Information Service, US Department of Commerce, Springfield, USA, Update n° 4. (2001). |
[3] | A. Fujishima, K. Honda, Nature. 238 (1972) 37-38. |
[4] | R.I. Subramanian, V.M. Kuno, P.V. Kamat, J. Am. Chem. Soc. 128 (2006) 2385-2393. |
[5] | J.Y. Shi, W.H. Leng, W.C. Zhu, Chem. Eng. Technol. 29 (2006) 146-154. |
[6] | T.A. McMurray, J.A. Byrne, P.S. Dunlop, J. Appl. Electrochem. 25 (2005) 723-731. |
[7] | C. Junshui, L. Meichuan, L.Z. Jidong, J. Environ. Manage. (2004) 43-47. |
[8] | C. He, Y. Xiong, Z. Xihai, Thin Solid Films. 422 (2002) 235-238. |
[9] | A. Taicheng, Z. Xihai, Y. Xiong, Mater. Phys. Mech. 4 (2001) 101-106. |
[10] | C.A. Morris, M.L. Anderson, R.M. Stroud, Science. 23 (1999) 622-624. |
[11] | A. Burns, W. Li, C. Baker, Res. Soc. Symp: Proc. 703 (2003) V.5.2.1. |
[12] | L. Davydov, F.P. Amaat, S.P. George, U.S. Patent, 6 (2003) 585, 863. |
[13] | A.M. Baraka, H.A. Hamed, H.H. Shaarawy, J. Anti-Corros. Method. Mater. 49 (2002) 282-286. |
[14] | I. Vrublevsky, V. Parkoun, V. Sokol, J. Schreckenbach, J. Appl. Surf. Sci. 236 (2004) 270-277. |
[15] | Vrublevsky, I. ; Parkoun, V. ; Schreckenbach, J. ; Max, G. J. Appl. Surf. Sci. 227 (2004) 282-292. |
[16] | I. Vrublevsky, V. Parkoun, V. Sokol, J. Schreckenbach, G. Max, J. Appl. Surf. Sci. 222 (2004) 215-225. |
[17] | J.R. Birch, T.D. Burleigh, J. Corrosion. 56 (2000) 1233-1241. |
[18] | R. Palombari, M. Ranchella, C. Rol, G.V. Sebastiani, J. Sol. Energ. Mat. Cell. 71 (2002) 359-368. |
[19] | J.C. Myland, K.B. Oldham, Anal. Chem. 72 (2000) 3210-3217. |
[20] | G.A. Ragoisha, A.S. Bondarenko, Electrochemistry : New research potentiodynamic electrochemical impedance spectroscopy, M. Nunez (Ed.), Nova Science Publ., New York. (2005) 51-75. |
[21] | T. Ohsaka, F. Izumi, Y. Fujiki, J. Raman Spectrosc. 7 (1978) 321-324. |
[22] | U. Balachandran, N.G. Eror, N.G., J. Solid State Chem. 42 (1982) 276-282. |
[23] | A. Linsbigler, C. Rusu, Y.T. Yates, J.Am.Chem.Soc. 118 (1996) 5284-5289. |
[24] | P.V. Kamat, J. Pure Appl. Chem. 74 (2002) 1693-1706. |
[25] | P.V. Kamat, J. Phys. Chem. B. 106 (2002) 7729-7744. |
[26] | T. Hirakawa, P.V. Kamat, J. Am. Chem. Soc. 127 (2005) 3928-3934. |
[27] | H. Gerischer, A. Heller, J. Phys. Chem. 95 (1991) 5261-5267. |
[28] | P.V. Kamat, Pure Appl. Chem. 74 (2002) 1693-1706. |
[29] | S.M. Mc Murry, Quantum Mechanics, Addison-Wesley Publishing Company Inc.(1994). |
APA Style
Gracien Bakambo Ekoko, Joseph Kanza-Kanza Lobo, Omer Muamba Mvele, Jérémie Lunguya Muswema, Jean-Félix Senga Yamambe. (2014). Effect of an External Applied Potential on the Photocatalytic Properties of Manganese-Doped Titanium Dioxide. American Journal of Physical Chemistry, 3(4), 41-46. https://doi.org/10.11648/j.ajpc.20140304.11
ACS Style
Gracien Bakambo Ekoko; Joseph Kanza-Kanza Lobo; Omer Muamba Mvele; Jérémie Lunguya Muswema; Jean-Félix Senga Yamambe. Effect of an External Applied Potential on the Photocatalytic Properties of Manganese-Doped Titanium Dioxide. Am. J. Phys. Chem. 2014, 3(4), 41-46. doi: 10.11648/j.ajpc.20140304.11
AMA Style
Gracien Bakambo Ekoko, Joseph Kanza-Kanza Lobo, Omer Muamba Mvele, Jérémie Lunguya Muswema, Jean-Félix Senga Yamambe. Effect of an External Applied Potential on the Photocatalytic Properties of Manganese-Doped Titanium Dioxide. Am J Phys Chem. 2014;3(4):41-46. doi: 10.11648/j.ajpc.20140304.11
@article{10.11648/j.ajpc.20140304.11, author = {Gracien Bakambo Ekoko and Joseph Kanza-Kanza Lobo and Omer Muamba Mvele and Jérémie Lunguya Muswema and Jean-Félix Senga Yamambe}, title = {Effect of an External Applied Potential on the Photocatalytic Properties of Manganese-Doped Titanium Dioxide}, journal = {American Journal of Physical Chemistry}, volume = {3}, number = {4}, pages = {41-46}, doi = {10.11648/j.ajpc.20140304.11}, url = {https://doi.org/10.11648/j.ajpc.20140304.11}, eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpc.20140304.11}, abstract = {The electrochemical anodic oxidation method was used to prepare thin films of titanium dioxide (TiO2) semiconductors (undoped and doped with Mn). These films were used to test the oxidation of methanol (CH3OH), the degree of which was quantified by measuring the current density produced as a function of an applied potential between 0.5 V and 5.0 V. The value of the potential to be applied in order to prevent fast electron-hole recombination was determined. The observed phenomenon is explained by considering the wave nature of the electron.}, year = {2014} }
TY - JOUR T1 - Effect of an External Applied Potential on the Photocatalytic Properties of Manganese-Doped Titanium Dioxide AU - Gracien Bakambo Ekoko AU - Joseph Kanza-Kanza Lobo AU - Omer Muamba Mvele AU - Jérémie Lunguya Muswema AU - Jean-Félix Senga Yamambe Y1 - 2014/08/30 PY - 2014 N1 - https://doi.org/10.11648/j.ajpc.20140304.11 DO - 10.11648/j.ajpc.20140304.11 T2 - American Journal of Physical Chemistry JF - American Journal of Physical Chemistry JO - American Journal of Physical Chemistry SP - 41 EP - 46 PB - Science Publishing Group SN - 2327-2449 UR - https://doi.org/10.11648/j.ajpc.20140304.11 AB - The electrochemical anodic oxidation method was used to prepare thin films of titanium dioxide (TiO2) semiconductors (undoped and doped with Mn). These films were used to test the oxidation of methanol (CH3OH), the degree of which was quantified by measuring the current density produced as a function of an applied potential between 0.5 V and 5.0 V. The value of the potential to be applied in order to prevent fast electron-hole recombination was determined. The observed phenomenon is explained by considering the wave nature of the electron. VL - 3 IS - 4 ER -