Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite

M. Y. Hassaan; H. H. El-Bahnasawy; S. M. Salem; T. Z. Amer; M. G. Moustafa; A. G. Mostafa

doi:doi:10.11648/j.am.20160505.14

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Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite

M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, A. G. Mostafa

Published in Advances in Materials (Volume 5, Issue 5)

Received: 7 September 2016 Accepted: 21 September 2016 Published: 11 October 2016

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Abstract

Glass sample with the composition 1 Li₂O • 0.25 Fe₂O₃• 0.25 V₂O₅• 1.5 SiO₂ has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.

Published in	Advances in Materials (Volume 5, Issue 5)
DOI	10.11648/j.am.20160505.14
Page(s)	51-56
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Lithium-Silicate Glasses, Glass-Ceramics, Sulfur Doped Glasses, Solid Batteries, Glass Cathode, Mössbauer Spectroscopy, X-ray Diffraction, Fourier-Transform Infrared, DC Electrical Conductivity

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APA Style

M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. (2016). Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Advances in Materials, 5(5), 51-56. https://doi.org/10.11648/j.am.20160505.14

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ACS Style

M. Y. Hassaan; H. H. El-Bahnasawy; S. M. Salem; T. Z. Amer; M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv. Mater. 2016, 5(5), 51-56. doi: 10.11648/j.am.20160505.14

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AMA Style

M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv Mater. 2016;5(5):51-56. doi: 10.11648/j.am.20160505.14

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@article{10.11648/j.am.20160505.14,
  author = {M. Y. Hassaan and H. H. El-Bahnasawy and S. M. Salem and T. Z. Amer and M. G. Moustafa and A. G. Mostafa},
  title = {Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite},
  journal = {Advances in Materials},
  volume = {5},
  number = {5},
  pages = {51-56},
  doi = {10.11648/j.am.20160505.14},
  url = {https://doi.org/10.11648/j.am.20160505.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20160505.14},
  abstract = {Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.},
 year = {2016}
}

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TY - JOUR
T1 - Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite
AU - M. Y. Hassaan
AU - H. H. El-Bahnasawy
AU - S. M. Salem
AU - T. Z. Amer
AU - M. G. Moustafa
AU - A. G. Mostafa
Y1 - 2016/10/11
PY - 2016
N1 - https://doi.org/10.11648/j.am.20160505.14
DO - 10.11648/j.am.20160505.14
T2 - Advances in Materials
JF - Advances in Materials
JO - Advances in Materials
SP - 51
EP - 56
PB - Science Publishing Group
SN - 2327-252X
UR - https://doi.org/10.11648/j.am.20160505.14
AB - Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.
VL - 5
IS - 5
ER -

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Author Information

M. Y. Hassaan

Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
H. H. El-Bahnasawy

Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
S. M. Salem

Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
T. Z. Amer

Phys. Department, Faculty of Science, Al-Azhar University, (Girls Branch) Nasr City, Cairo, Egypt
M. G. Moustafa

Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
A. G. Mostafa

Phys. Department, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

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APA Style

M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. (2016). Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Advances in Materials, 5(5), 51-56. https://doi.org/10.11648/j.am.20160505.14

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ACS Style

M. Y. Hassaan; H. H. El-Bahnasawy; S. M. Salem; T. Z. Amer; M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv. Mater. 2016, 5(5), 51-56. doi: 10.11648/j.am.20160505.14

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AMA Style

M. Y. Hassaan, H. H. El-Bahnasawy, S. M. Salem, T. Z. Amer, M. G. Moustafa, et al. Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite. Adv Mater. 2016;5(5):51-56. doi: 10.11648/j.am.20160505.14

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@article{10.11648/j.am.20160505.14,
  author = {M. Y. Hassaan and H. H. El-Bahnasawy and S. M. Salem and T. Z. Amer and M. G. Moustafa and A. G. Mostafa},
  title = {Effect of Sulfur on the Structure and Physical Properties of Vanadium-Iron-Lithium-Silicate Glass and Glass-Ceramics Nano Composite},
  journal = {Advances in Materials},
  volume = {5},
  number = {5},
  pages = {51-56},
  doi = {10.11648/j.am.20160505.14},
  url = {https://doi.org/10.11648/j.am.20160505.14},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.am.20160505.14},
  abstract = {Glass sample with the composition 1 Li2O • 0.25 Fe2O3• 0.25 V2O5• 1.5 SiO2 has been studied for the usage as a cathode material in solid batteries. Another sample with the previous composition in addition to 5wt. % sulfur as reduced agent to yelled multi-valance Fe and V ions was also studied. Both sulfur-free and sulfur-doped glass samples were subjected to heat treatment for one hour at 550°C to obtain two glass–ceramic samples. Structural studies were made using X-ray diffraction (XRD), Mössbauer effect (ME) and Fourier-transform infrared spectroscopy (FT-IR). The precipitation of various phases in heat treated glass samples with particle size in the nano-range was observed in X-ray pattern. Mössbauer spectra indicated that iron exist as a ferric ions occupy two non-equivalent tetrahedral sites in the sulfur-free samples, while ferrous ions in octahedral site in addition to the previous two ferric phases was appeared in sulfur-doped samples. Differential thermal analysis (DTA) was also carried out to monitor the crystallization temperature and the thermal stability of the obtained glasses. DC electrical conductivity measurements exhibit an enhancement of the conductivity of sulfur-doped glass sample compared with sulfur-free which make it more suitable to use as cathode in the solid batteries.},
 year = {2016}
}

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