Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon

Hao Ma; Xingxiang Ji; Zhongjian Tian; Guigan Fang; Guihua Yang

doi:doi:10.11648/j.jenr.20170602.12

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Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon

Hao Ma, Xingxiang Ji, Zhongjian Tian, Guigan Fang, Guihua Yang

Published in Journal of Energy and Natural Resources (Volume 6, Issue 2)

Received: 10 May 2017 Published: 10 May 2017

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Abstract

The effects of modification on the surface properties and inhibiting compounds (formic acid, acetic acid, 5-hydroxymethylfurfural and furfural) removal performance of activate carbon (AC) were investigated. The raw and modified ACs were characterized, the result showed that the surface chemistries of the modified ACs were significant changed, but only the porous structure of modified by HNO₃ were slightly damaged, and the others no obvious change. The formic acid and acetic acid removal performance of modified AC had a certain amount of improvement compared to the raw AC, but it is still relatively low (15% and 14%), so AC adsorption is not suitable for removal formic acid and acetic acid. And the 5-hydroxymethylfurfural (5-HMF) and furfural removal performance of modified AC by ZNCl₂ is good (89% and 81%). the process of adsorption of 5-HMF and furfural by activated carbon belongs to the process of exothermic physical adsorption and is the entropy reduction process. The adsorption is best carried out at low temperature.

Published in	Journal of Energy and Natural Resources (Volume 6, Issue 2)
DOI	10.11648/j.jenr.20170602.12
Page(s)	24-30
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2017. Published by Science Publishing Group

Keywords

Inhibiting Compounds, Modified Active Carbon, Adsorption, Kinetics, Isotherms

References

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[8]	Liu H, Hu H, Jahan M. S, et al. Purification of Hemicelluloses in Pre-Hydrolysis Liquor of Kraft-Based Dissolving Pulp Production Process Using Activated Carbon and Ion-Exchange Resin Adsorption Followed by Nanofiltration [J]. Journal of Biobased Materials & Bioenergy, 2014, 8(3): 325-330(6).
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[10]	Yao S, Zhang J, Shen D, et al. Removal of Pb(II) from water by the activated carbon modified by nitric acid under microwave heating [J]. J Colloid Interface Sci, 2016, 463: 118-27.
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[12]	Wang Z, Zhuang J, Wang X, et al. Limited adsorption selectivity of active carbon toward non-saccharide compounds in lignocellulose hydrolysate [J]. Bioresour Technol, 2016, 208: 195-9.
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APA Style

Hao Ma, Xingxiang Ji, Zhongjian Tian, Guigan Fang, Guihua Yang. (2017). Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. Journal of Energy and Natural Resources, 6(2), 24-30. https://doi.org/10.11648/j.jenr.20170602.12

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ACS Style

Hao Ma; Xingxiang Ji; Zhongjian Tian; Guigan Fang; Guihua Yang. Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. J. Energy Nat. Resour. 2017, 6(2), 24-30. doi: 10.11648/j.jenr.20170602.12

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AMA Style

Hao Ma, Xingxiang Ji, Zhongjian Tian, Guigan Fang, Guihua Yang. Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. J Energy Nat Resour. 2017;6(2):24-30. doi: 10.11648/j.jenr.20170602.12

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@article{10.11648/j.jenr.20170602.12,
  author = {Hao Ma and Xingxiang Ji and Zhongjian Tian and Guigan Fang and Guihua Yang},
  title = {Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon},
  journal = {Journal of Energy and Natural Resources},
  volume = {6},
  number = {2},
  pages = {24-30},
  doi = {10.11648/j.jenr.20170602.12},
  url = {https://doi.org/10.11648/j.jenr.20170602.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20170602.12},
  abstract = {The effects of modification on the surface properties and inhibiting compounds (formic acid, acetic acid, 5-hydroxymethylfurfural and furfural) removal performance of activate carbon (AC) were investigated. The raw and modified ACs were characterized, the result showed that the surface chemistries of the modified ACs were significant changed, but only the porous structure of modified by HNO3 were slightly damaged, and the others no obvious change. The formic acid and acetic acid removal performance of modified AC had a certain amount of improvement compared to the raw AC, but it is still relatively low (15% and 14%), so AC adsorption is not suitable for removal formic acid and acetic acid. And the 5-hydroxymethylfurfural (5-HMF) and furfural removal performance of modified AC by ZNCl2 is good (89% and 81%). the process of adsorption of 5-HMF and furfural by activated carbon belongs to the process of exothermic physical adsorption and is the entropy reduction process. The adsorption is best carried out at low temperature.},
 year = {2017}
}

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TY  - JOUR
T1  - Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon
AU  - Hao Ma
AU  - Xingxiang Ji
AU  - Zhongjian Tian
AU  - Guigan Fang
AU  - Guihua Yang
Y1  - 2017/05/10
PY  - 2017
N1  - https://doi.org/10.11648/j.jenr.20170602.12
DO  - 10.11648/j.jenr.20170602.12
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 24
EP  - 30
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20170602.12
AB  - The effects of modification on the surface properties and inhibiting compounds (formic acid, acetic acid, 5-hydroxymethylfurfural and furfural) removal performance of activate carbon (AC) were investigated. The raw and modified ACs were characterized, the result showed that the surface chemistries of the modified ACs were significant changed, but only the porous structure of modified by HNO3 were slightly damaged, and the others no obvious change. The formic acid and acetic acid removal performance of modified AC had a certain amount of improvement compared to the raw AC, but it is still relatively low (15% and 14%), so AC adsorption is not suitable for removal formic acid and acetic acid. And the 5-hydroxymethylfurfural (5-HMF) and furfural removal performance of modified AC by ZNCl2 is good (89% and 81%). the process of adsorption of 5-HMF and furfural by activated carbon belongs to the process of exothermic physical adsorption and is the entropy reduction process. The adsorption is best carried out at low temperature.
VL  - 6
IS  - 2
ER  -

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Author Information

Hao Ma

Key Lab of Pulp and Paper Science & Technology, Ministry of Education, Qilu University of Technology, Ji’nan, China
Xingxiang Ji

Key Lab of Pulp and Paper Science & Technology, Ministry of Education, Qilu University of Technology, Ji’nan, China
Zhongjian Tian

Key Lab of Pulp and Paper Science & Technology, Ministry of Education, Qilu University of Technology, Ji’nan, China
Guigan Fang

Institute of Chemical Industry of Forestry Products, Nanjing, China
Guihua Yang

Key Lab of Pulp and Paper Science & Technology, Ministry of Education, Qilu University of Technology, Ji’nan, China

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Plain Text BibTeX RIS

APA Style

Hao Ma, Xingxiang Ji, Zhongjian Tian, Guigan Fang, Guihua Yang. (2017). Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. Journal of Energy and Natural Resources, 6(2), 24-30. https://doi.org/10.11648/j.jenr.20170602.12

Copy | Download

ACS Style

Hao Ma; Xingxiang Ji; Zhongjian Tian; Guigan Fang; Guihua Yang. Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. J. Energy Nat. Resour. 2017, 6(2), 24-30. doi: 10.11648/j.jenr.20170602.12

Copy | Download

AMA Style

Hao Ma, Xingxiang Ji, Zhongjian Tian, Guigan Fang, Guihua Yang. Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon. J Energy Nat Resour. 2017;6(2):24-30. doi: 10.11648/j.jenr.20170602.12

Copy | Download

@article{10.11648/j.jenr.20170602.12,
  author = {Hao Ma and Xingxiang Ji and Zhongjian Tian and Guigan Fang and Guihua Yang},
  title = {Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon},
  journal = {Journal of Energy and Natural Resources},
  volume = {6},
  number = {2},
  pages = {24-30},
  doi = {10.11648/j.jenr.20170602.12},
  url = {https://doi.org/10.11648/j.jenr.20170602.12},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.jenr.20170602.12},
  abstract = {The effects of modification on the surface properties and inhibiting compounds (formic acid, acetic acid, 5-hydroxymethylfurfural and furfural) removal performance of activate carbon (AC) were investigated. The raw and modified ACs were characterized, the result showed that the surface chemistries of the modified ACs were significant changed, but only the porous structure of modified by HNO3 were slightly damaged, and the others no obvious change. The formic acid and acetic acid removal performance of modified AC had a certain amount of improvement compared to the raw AC, but it is still relatively low (15% and 14%), so AC adsorption is not suitable for removal formic acid and acetic acid. And the 5-hydroxymethylfurfural (5-HMF) and furfural removal performance of modified AC by ZNCl2 is good (89% and 81%). the process of adsorption of 5-HMF and furfural by activated carbon belongs to the process of exothermic physical adsorption and is the entropy reduction process. The adsorption is best carried out at low temperature.},
 year = {2017}
}

Copy | Download

TY  - JOUR
T1  - Adsorption Removal of Inhibiting Compounds by Modified Activated Carbon
AU  - Hao Ma
AU  - Xingxiang Ji
AU  - Zhongjian Tian
AU  - Guigan Fang
AU  - Guihua Yang
Y1  - 2017/05/10
PY  - 2017
N1  - https://doi.org/10.11648/j.jenr.20170602.12
DO  - 10.11648/j.jenr.20170602.12
T2  - Journal of Energy and Natural Resources
JF  - Journal of Energy and Natural Resources
JO  - Journal of Energy and Natural Resources
SP  - 24
EP  - 30
PB  - Science Publishing Group
SN  - 2330-7404
UR  - https://doi.org/10.11648/j.jenr.20170602.12
AB  - The effects of modification on the surface properties and inhibiting compounds (formic acid, acetic acid, 5-hydroxymethylfurfural and furfural) removal performance of activate carbon (AC) were investigated. The raw and modified ACs were characterized, the result showed that the surface chemistries of the modified ACs were significant changed, but only the porous structure of modified by HNO3 were slightly damaged, and the others no obvious change. The formic acid and acetic acid removal performance of modified AC had a certain amount of improvement compared to the raw AC, but it is still relatively low (15% and 14%), so AC adsorption is not suitable for removal formic acid and acetic acid. And the 5-hydroxymethylfurfural (5-HMF) and furfural removal performance of modified AC by ZNCl2 is good (89% and 81%). the process of adsorption of 5-HMF and furfural by activated carbon belongs to the process of exothermic physical adsorption and is the entropy reduction process. The adsorption is best carried out at low temperature.
VL  - 6
IS  - 2
ER  -

Copy | Download