Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent

Chiraz Ammar; Yassine El Ghoul; Ahmida El Achari

doi:doi:10.11648/j.nano.s.2015030401.15

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Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent

Chiraz Ammar, Yassine El Ghoul, Ahmida El Achari

Published in American Journal of Nano Research and Applications (Volume 3, Issue 4-1)

Received: 25 March 2015 Accepted: 25 March 2015 Published: 8 April 2015

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Abstract

This study describes the use of cyclodextrin (CDs) as a finishing agent of polypropylene biomaterial (PP) by means of 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinking agent. Grafting happened by the formation of a crosslinked polymer formed between BTCA and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. We study the influence of parameters involved in this specific textile processing. These parameters include the curing conditions (temperature, time) and also the nature of the reactants which are 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CTR) and polyacrylic acid (PAA), applied as crosslinking agents. Modified PP fibers were then characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PP fibers (Cahn balance) with various grafting rates. Infrared spectroscopy (ATR) and morphological (SEM) studies displayed the presence of the crosslinked CD polymer that coated the fibers, and permitted to evaluate the chemical heterogeneity of the grafted surfaces. A mechanical characterization of the PP fabrics grafted with various proportions of CDs was accomplished, by traction via a tensile-test. Finally a topographic study of PP grafted surfaces was approached by atomic force microscopy (AFM) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces.

Published in	American Journal of Nano Research and Applications (Volume 3, Issue 4-1) This article belongs to the Special Issue Nanocomposites Coating and Manufacturing
DOI	10.11648/j.nano.s.2015030401.15
Page(s)	25-30
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Polypropylene, Fibers, Cyclodextrin Polymer, BTCA Acid, Grafting

References

[1]	H. Dodzuik (2006), ed. Wiley-VCH, Cyclodextrins and their complexes, Weinheim, ISBN 3-527-31280-3.
[2]	S. M. Gawish, S. R. Matthews, D. M. Wafa, F. Breidt, and M. A. Bourham (2007), J. Appl. Polym. Sci., Vol. 103, p. 1900.
[3]	S. Salmaso, A. Semenzato, P. CalicetiJohan, H. Sonvico, C. Dubernet, P. Couvreur (2004), Bioconjugate Chem., 15 (5), p. 997.
[4]	T. Loftsson, D. Duchêne (2007), International Journal of Pharmaceutics, 329, 1.
[5]	R. Breslow, S. D. Dong (1998), Biomimetic reactions catalysed by cyclodextrins and their derivatives. Chem. Rev. 98, 1997-2012.
[6]	J. Szejtli, B. Zsadon, E. Fenyvesi, O. Horvarth, and F. Tudos (1982), US Patent 4, 357, 468.
[7]	K. Poulakis, H.J. Buschmann, and E. Schollmeyer (1992), German Patent DE 40 35 378 A1.
[8]	U. Denter and E. Schollmeyer: in J. Szejtli and L. Szente (1996), Proc. VIIIth Int. Cycl. Symp. Budapest, pp. 553-558.
[9]	P. Le Thuaut, B. Martel, G. Crini, U. Maschke, X. Coqueret and M. Morcellet (2000), J. Appl. Polym. Sci., 77, 2118.
[10]	B. Martel, M. Weltrowski, D. Ruffin, and M. Morcellet (2002), J. Appl. Polym. Sci., 83, 1449.
[11]	Y. El Ghoul, B. Martel, M. Morcellet, C. Campagne, A. El Achari, and S. Roudesli (2007), J. Incl. Phenom. Macrocycl. Chem., 57, 47.
[12]	M.Weltrowski, M. Morcellet, and B. Martel, FR 9901967 (2000), DE 600 10 055 T2 (2005), EP 1,157,156 B1 (2004); US 7,048,769B1 (2006), CA 2,362,534, WO 0047811.
[13]	B. Martel, D. Ruffin, J. M. Hougard, and M. Morcellet (2004), Proc. XIIth International Cyclodextrin Symposium, Montpellier, May 16-19, 639.
[14]	N. Blanchemain, S. Haulon, B. Martel, M. Traisnel, M. Morcellet, and H. F. Hildebrand (2005), Eur. J. Vasc. Endovasc. Surg. 29, 628.
[15]	M. Weltrowski, B. Martel, and M. Morcellet (2001), Patent PCT 00378 (2000), US 09/913,448 (2001), CA 2,362,534.
[16]	N. Blanchemain, T. Laurent, F. Chai, C. Neut, S. Haulon, V. Krump-Konvalinkova, M. Morcellet, B. Martel, C. J. Kirkpatrick, and H. F. Hildebrand (2008), Acta Biomaterialia 4, 1725.
[17]	F. Boschin, N. Blanchemain, M. Bria, E. Delcourt-Debruyne, M. Morcellet, and H. F. Hildebrand (2006), J. of Biomed. Mater. Res.: Part A., 79, 78.
[18]	Y. El Ghoul, N. Blanchemain, C. Campagne, A. El Achari, S. Roudesli, M. Morcellet, B. Martel, and H. F. Hildebrand (2008), Acta Biomaterialia, 4, 1392.
[19]	Y. El Ghoul, B. Martel, A. El Achari, C. Campagne, L. Razafimahefa, and I. Vroman (2010), Polymer Journal 42, 804.

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APA Style

Chiraz Ammar, Yassine El Ghoul, Ahmida El Achari. (2015). Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. American Journal of Nano Research and Applications, 3(4-1), 25-30. https://doi.org/10.11648/j.nano.s.2015030401.15

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ACS Style

Chiraz Ammar; Yassine El Ghoul; Ahmida El Achari. Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. Am. J. Nano Res. Appl. 2015, 3(4-1), 25-30. doi: 10.11648/j.nano.s.2015030401.15

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AMA Style

Chiraz Ammar, Yassine El Ghoul, Ahmida El Achari. Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. Am J Nano Res Appl. 2015;3(4-1):25-30. doi: 10.11648/j.nano.s.2015030401.15

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@article{10.11648/j.nano.s.2015030401.15,
  author = {Chiraz Ammar and Yassine El Ghoul and Ahmida El Achari},
  title = {Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent},
  journal = {American Journal of Nano Research and Applications},
  volume = {3},
  number = {4-1},
  pages = {25-30},
  doi = {10.11648/j.nano.s.2015030401.15},
  url = {https://doi.org/10.11648/j.nano.s.2015030401.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2015030401.15},
  abstract = {This study describes the use of cyclodextrin (CDs) as a finishing agent of polypropylene biomaterial (PP) by means of 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinking agent. Grafting happened by the formation of a crosslinked polymer formed between BTCA and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. We study the influence of parameters involved in this specific textile processing. These parameters include the curing conditions (temperature, time) and also the nature of the reactants which are 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CTR) and polyacrylic acid (PAA), applied as crosslinking agents. Modified PP fibers were then characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PP fibers (Cahn balance) with various grafting rates. Infrared spectroscopy (ATR) and morphological (SEM) studies displayed the presence of the crosslinked CD polymer that coated the fibers, and permitted to evaluate the chemical heterogeneity of the grafted surfaces. A mechanical characterization of the PP fabrics grafted with various proportions of CDs was accomplished, by traction via a tensile-test. Finally a topographic study of PP grafted surfaces was approached by atomic force microscopy (AFM) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces.},
 year = {2015}
}

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TY  - JOUR
T1  - Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent
AU  - Chiraz Ammar
AU  - Yassine El Ghoul
AU  - Ahmida El Achari
Y1  - 2015/04/08
PY  - 2015
N1  - https://doi.org/10.11648/j.nano.s.2015030401.15
DO  - 10.11648/j.nano.s.2015030401.15
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 25
EP  - 30
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.s.2015030401.15
AB  - This study describes the use of cyclodextrin (CDs) as a finishing agent of polypropylene biomaterial (PP) by means of 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinking agent. Grafting happened by the formation of a crosslinked polymer formed between BTCA and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. We study the influence of parameters involved in this specific textile processing. These parameters include the curing conditions (temperature, time) and also the nature of the reactants which are 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CTR) and polyacrylic acid (PAA), applied as crosslinking agents. Modified PP fibers were then characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PP fibers (Cahn balance) with various grafting rates. Infrared spectroscopy (ATR) and morphological (SEM) studies displayed the presence of the crosslinked CD polymer that coated the fibers, and permitted to evaluate the chemical heterogeneity of the grafted surfaces. A mechanical characterization of the PP fabrics grafted with various proportions of CDs was accomplished, by traction via a tensile-test. Finally a topographic study of PP grafted surfaces was approached by atomic force microscopy (AFM) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces.
VL  - 3
IS  - 4-1
ER  -

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Author Information

Chiraz Ammar

Laboratory of Engineering Textile, ISET of Ksar Hellal, Monastir, Tunisia
Yassine El Ghoul

Laboratory of Engineering Textile, ISET of Ksar Hellal, Monastir, Tunisia
Ahmida El Achari

Laboratory of Textile Process and Materials, UPRES EA 2161, Research Unit of ENSAIT, B.P 30329, 59056 Roubaix cedex 01, Roubaix, France

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APA Style

Chiraz Ammar, Yassine El Ghoul, Ahmida El Achari. (2015). Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. American Journal of Nano Research and Applications, 3(4-1), 25-30. https://doi.org/10.11648/j.nano.s.2015030401.15

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ACS Style

Chiraz Ammar; Yassine El Ghoul; Ahmida El Achari. Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. Am. J. Nano Res. Appl. 2015, 3(4-1), 25-30. doi: 10.11648/j.nano.s.2015030401.15

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AMA Style

Chiraz Ammar, Yassine El Ghoul, Ahmida El Achari. Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent. Am J Nano Res Appl. 2015;3(4-1):25-30. doi: 10.11648/j.nano.s.2015030401.15

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@article{10.11648/j.nano.s.2015030401.15,
  author = {Chiraz Ammar and Yassine El Ghoul and Ahmida El Achari},
  title = {Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent},
  journal = {American Journal of Nano Research and Applications},
  volume = {3},
  number = {4-1},
  pages = {25-30},
  doi = {10.11648/j.nano.s.2015030401.15},
  url = {https://doi.org/10.11648/j.nano.s.2015030401.15},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.nano.s.2015030401.15},
  abstract = {This study describes the use of cyclodextrin (CDs) as a finishing agent of polypropylene biomaterial (PP) by means of 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinking agent. Grafting happened by the formation of a crosslinked polymer formed between BTCA and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. We study the influence of parameters involved in this specific textile processing. These parameters include the curing conditions (temperature, time) and also the nature of the reactants which are 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CTR) and polyacrylic acid (PAA), applied as crosslinking agents. Modified PP fibers were then characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PP fibers (Cahn balance) with various grafting rates. Infrared spectroscopy (ATR) and morphological (SEM) studies displayed the presence of the crosslinked CD polymer that coated the fibers, and permitted to evaluate the chemical heterogeneity of the grafted surfaces. A mechanical characterization of the PP fabrics grafted with various proportions of CDs was accomplished, by traction via a tensile-test. Finally a topographic study of PP grafted surfaces was approached by atomic force microscopy (AFM) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces.},
 year = {2015}
}

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TY  - JOUR
T1  - Polypropylene Biomaterial Grafted with Cyclodextrins and BTCA Acid as Crosslinking Agent
AU  - Chiraz Ammar
AU  - Yassine El Ghoul
AU  - Ahmida El Achari
Y1  - 2015/04/08
PY  - 2015
N1  - https://doi.org/10.11648/j.nano.s.2015030401.15
DO  - 10.11648/j.nano.s.2015030401.15
T2  - American Journal of Nano Research and Applications
JF  - American Journal of Nano Research and Applications
JO  - American Journal of Nano Research and Applications
SP  - 25
EP  - 30
PB  - Science Publishing Group
SN  - 2575-3738
UR  - https://doi.org/10.11648/j.nano.s.2015030401.15
AB  - This study describes the use of cyclodextrin (CDs) as a finishing agent of polypropylene biomaterial (PP) by means of 1,2,3,4-butanetetracarboxylic acid (BTCA) as crosslinking agent. Grafting happened by the formation of a crosslinked polymer formed between BTCA and CDs. This polymer physically adhered to the fibers network and was resistant to hot water washings. We study the influence of parameters involved in this specific textile processing. These parameters include the curing conditions (temperature, time) and also the nature of the reactants which are 1,2,3,4-butanetetracarboxylic acid (BTCA), citric acid (CTR) and polyacrylic acid (PAA), applied as crosslinking agents. Modified PP fibers were then characterized by evaluating the contact angle with a polar liquid and by studying the hysteresis of damping of PP fibers (Cahn balance) with various grafting rates. Infrared spectroscopy (ATR) and morphological (SEM) studies displayed the presence of the crosslinked CD polymer that coated the fibers, and permitted to evaluate the chemical heterogeneity of the grafted surfaces. A mechanical characterization of the PP fabrics grafted with various proportions of CDs was accomplished, by traction via a tensile-test. Finally a topographic study of PP grafted surfaces was approached by atomic force microscopy (AFM) which permitted to evaluate the roughness and the chemical heterogeneity of the grafted surfaces.
VL  - 3
IS  - 4-1
ER  -

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