Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses

H. A. Saudi; S. M. Salem; S. S. Mohammad; A. G. Mostafa; M. Y. Hassaan

doi:doi:10.11648/j.ajpa.20150303.16

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Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses

H. A. Saudi, S. M. Salem, S. S. Mohammad, A. G. Mostafa, M. Y. Hassaan

Published in American Journal of Physics and Applications (Volume 3, Issue 3)

Received: 7 May 2015 Accepted: 15 May 2015 Published: 26 May 2015

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Abstract

Egyptian rice husk was subjected to different chemical and thermal treatment methods, aiming to extract high pure silica. Three samples (S1, S2 and S3) were prepared applying three different chemical treatment methods. Two sets of the obtained samples were prepared, where the first set was calcinated at 600oC and the other set was calcinated at 750 oC by slow heating (starting at RT and ending at the desired calcinations temperature for 2 h).XRF was applied to identify the chemical composition and purity of the extracted silica, while XRD was applied to confirm the amorphous nature and the presence of some induced carbon black in the obtained silica. It was found that S3 slowly heated at 750 oC presents the highest silica content (98.6 %). Such sample was fed directly to the calcinations furnace at 750 oC (sudden heating for comparison) where it presents only 90.6% silica, and 3.74 % residual carbon black. However, the extracted silica from sample S3 was used to prepare glasses obeying the composition (75-x) mol% RH-silica, x mol% Bi2O3, 25 mol% Na2O, (where 0 ≤ x ≤ 20).FTIR spectroscopic analysis was applied to investigate the internal structure of the prepared glasses, where the glass networks were found to contain mainly SiO4, BiO3 and BiO6 structural groups, as well as some bridging and non-bridging oxygen anions. Also, some O-H and H-O-H groups were also detected which may be due to the used KBr disk technique.

Published in	American Journal of Physics and Applications (Volume 3, Issue 3)
DOI	10.11648/j.ajpa.20150303.16
Page(s)	97-105
Creative Commons	This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.
Copyright	Copyright © The Author(s), 2015. Published by Science Publishing Group

Keywords

Silica from Rice Husk, Silicate Glasses, Bi-Na-Silicate Glass, XRD, XRF, Infrared Spectroscopy

References

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APA Style

H. A. Saudi, S. M. Salem, S. S. Mohammad, A. G. Mostafa, M. Y. Hassaan. (2015). Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. American Journal of Physics and Applications, 3(3), 97-105. https://doi.org/10.11648/j.ajpa.20150303.16

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ACS Style

H. A. Saudi; S. M. Salem; S. S. Mohammad; A. G. Mostafa; M. Y. Hassaan. Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. Am. J. Phys. Appl. 2015, 3(3), 97-105. doi: 10.11648/j.ajpa.20150303.16

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AMA Style

H. A. Saudi, S. M. Salem, S. S. Mohammad, A. G. Mostafa, M. Y. Hassaan. Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. Am J Phys Appl. 2015;3(3):97-105. doi: 10.11648/j.ajpa.20150303.16

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@article{10.11648/j.ajpa.20150303.16,
  author = {H. A. Saudi and S. M. Salem and S. S. Mohammad and A. G. Mostafa and M. Y. Hassaan},
  title = {Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses},
  journal = {American Journal of Physics and Applications},
  volume = {3},
  number = {3},
  pages = {97-105},
  doi = {10.11648/j.ajpa.20150303.16},
  url = {https://doi.org/10.11648/j.ajpa.20150303.16},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20150303.16},
  abstract = {Egyptian rice husk was subjected to different chemical and thermal treatment methods, aiming to extract high pure silica. Three samples (S1, S2 and S3) were prepared applying three different chemical treatment methods. Two sets of the obtained samples were prepared, where the first set was calcinated at 600oC and the other set was calcinated at 750 oC by slow heating (starting at RT and ending at the desired calcinations temperature for 2 h).XRF was applied to identify the chemical composition and purity of the extracted silica, while XRD was applied to confirm the amorphous nature and the presence of some induced carbon black in the obtained silica. It was found that S3 slowly heated at 750 oC presents the highest silica content (98.6 %). Such sample was fed directly to the calcinations furnace at 750 oC (sudden heating for comparison) where it presents only 90.6% silica, and 3.74 % residual carbon black. However, the extracted silica from sample S3 was used to prepare glasses obeying the composition (75-x) mol% RH-silica, x mol% Bi2O3, 25 mol% Na2O, (where 0 ≤ x ≤ 20).FTIR spectroscopic analysis was applied to investigate the internal structure of the prepared glasses, where the glass networks were found to contain mainly SiO4, BiO3 and BiO6 structural groups, as well as some bridging and non-bridging oxygen anions. Also, some O-H and H-O-H groups were also detected which may be due to the used KBr disk technique.},
 year = {2015}
}

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TY - JOUR
T1 - Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses
AU - H. A. Saudi
AU - S. M. Salem
AU - S. S. Mohammad
AU - A. G. Mostafa
AU - M. Y. Hassaan
Y1 - 2015/05/26
PY - 2015
N1 - https://doi.org/10.11648/j.ajpa.20150303.16
DO - 10.11648/j.ajpa.20150303.16
T2 - American Journal of Physics and Applications
JF - American Journal of Physics and Applications
JO - American Journal of Physics and Applications
SP - 97
EP - 105
PB - Science Publishing Group
SN - 2330-4308
UR - https://doi.org/10.11648/j.ajpa.20150303.16
AB - Egyptian rice husk was subjected to different chemical and thermal treatment methods, aiming to extract high pure silica. Three samples (S1, S2 and S3) were prepared applying three different chemical treatment methods. Two sets of the obtained samples were prepared, where the first set was calcinated at 600oC and the other set was calcinated at 750 oC by slow heating (starting at RT and ending at the desired calcinations temperature for 2 h).XRF was applied to identify the chemical composition and purity of the extracted silica, while XRD was applied to confirm the amorphous nature and the presence of some induced carbon black in the obtained silica. It was found that S3 slowly heated at 750 oC presents the highest silica content (98.6 %). Such sample was fed directly to the calcinations furnace at 750 oC (sudden heating for comparison) where it presents only 90.6% silica, and 3.74 % residual carbon black. However, the extracted silica from sample S3 was used to prepare glasses obeying the composition (75-x) mol% RH-silica, x mol% Bi2O3, 25 mol% Na2O, (where 0 ≤ x ≤ 20).FTIR spectroscopic analysis was applied to investigate the internal structure of the prepared glasses, where the glass networks were found to contain mainly SiO4, BiO3 and BiO6 structural groups, as well as some bridging and non-bridging oxygen anions. Also, some O-H and H-O-H groups were also detected which may be due to the used KBr disk technique.
VL - 3
IS - 3
ER -

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Author Information

H. A. Saudi

Department of Physics, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt
S. M. Salem

Department of Physics, Faculty of Science (Girls' Branch), Al-Azhar University, Nasr City, Cairo, Egypt
S. S. Mohammad

Department of Physics, Faculty of Science (Girls' Branch), Al-Azhar University, Nasr City, Cairo, Egypt
A. G. Mostafa

Department of Physics, Faculty of Science (Girls' Branch), Al-Azhar University, Nasr City, Cairo, Egypt
M. Y. Hassaan

Department of Physics, Faculty of Science (Girls' Branch), Al-Azhar University, Nasr City, Cairo, Egypt

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APA Style

H. A. Saudi, S. M. Salem, S. S. Mohammad, A. G. Mostafa, M. Y. Hassaan. (2015). Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. American Journal of Physics and Applications, 3(3), 97-105. https://doi.org/10.11648/j.ajpa.20150303.16

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ACS Style

H. A. Saudi; S. M. Salem; S. S. Mohammad; A. G. Mostafa; M. Y. Hassaan. Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. Am. J. Phys. Appl. 2015, 3(3), 97-105. doi: 10.11648/j.ajpa.20150303.16

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AMA Style

H. A. Saudi, S. M. Salem, S. S. Mohammad, A. G. Mostafa, M. Y. Hassaan. Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses. Am J Phys Appl. 2015;3(3):97-105. doi: 10.11648/j.ajpa.20150303.16

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@article{10.11648/j.ajpa.20150303.16,
  author = {H. A. Saudi and S. M. Salem and S. S. Mohammad and A. G. Mostafa and M. Y. Hassaan},
  title = {Utilization of Pure Silica Extracted from Rice Husk and FTIR Structural Analysis of the Prepared Glasses},
  journal = {American Journal of Physics and Applications},
  volume = {3},
  number = {3},
  pages = {97-105},
  doi = {10.11648/j.ajpa.20150303.16},
  url = {https://doi.org/10.11648/j.ajpa.20150303.16},
  eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20150303.16},
  abstract = {Egyptian rice husk was subjected to different chemical and thermal treatment methods, aiming to extract high pure silica. Three samples (S1, S2 and S3) were prepared applying three different chemical treatment methods. Two sets of the obtained samples were prepared, where the first set was calcinated at 600oC and the other set was calcinated at 750 oC by slow heating (starting at RT and ending at the desired calcinations temperature for 2 h).XRF was applied to identify the chemical composition and purity of the extracted silica, while XRD was applied to confirm the amorphous nature and the presence of some induced carbon black in the obtained silica. It was found that S3 slowly heated at 750 oC presents the highest silica content (98.6 %). Such sample was fed directly to the calcinations furnace at 750 oC (sudden heating for comparison) where it presents only 90.6% silica, and 3.74 % residual carbon black. However, the extracted silica from sample S3 was used to prepare glasses obeying the composition (75-x) mol% RH-silica, x mol% Bi2O3, 25 mol% Na2O, (where 0 ≤ x ≤ 20).FTIR spectroscopic analysis was applied to investigate the internal structure of the prepared glasses, where the glass networks were found to contain mainly SiO4, BiO3 and BiO6 structural groups, as well as some bridging and non-bridging oxygen anions. Also, some O-H and H-O-H groups were also detected which may be due to the used KBr disk technique.},
 year = {2015}
}

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