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Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil

Received: 13 February 2016     Accepted: 17 May 2016     Published: 7 June 2016
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Abstract

The fluorescence spectroscopy (FS) is increasingly used in petroleum technology due the availability of better optical detection techniques, because FS offers high sensitivity, good diagnostic potential, and relatively simple instrumentation. Absorption and fluorescence spectrum of crude oil was studied at room temperature using optical path cuvette 1 cm. In this work, the absorption spectra were scanned (190-1100) nm while the emission spectra were obtained at different excitation wavelengths (266, 337, 420, and 488) nm. Crude oil was diluted by absolute ethanol to prepare different concentrations of crude oil. Ethanol as a solvent was used to dilute crude oil to obtain a solution transparent and the light could be transmitted. This work considers as an additional spectroscopic tool to develop into a fast responsive system for charchtrize the crude oil.

Published in American Journal of Physics and Applications (Volume 4, Issue 3)
DOI 10.11648/j.ajpa.20160403.12
Page(s) 78-83
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Fluorescence Spectroscopy, Crude Oil, UV-Vis Spectroscopy

References
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[2] Evdokimov I. N. and Losev A. P.," On the Nature of UV/Vis Absorption Spectra of Asphaltenes". Petroleum Science and Technology Vol. 25, Issue 1-2, 2007.
[3] F. Falla Sotelo, P. Araujo Pantoja, J. López-Gejo, G. A. C. Le Roux, F. H. Quina and C. A. O. Nascimento, "Application of Fluorescence Spectroscopy for Spectral Discrimination of Crude Oil Samples", Brazilian Journal of Petroleum and Gas. vol. 2, no. 2, p. 63-71, 2008.
[4] A. Stelmaszewski, "Fluorescence method for the determination of oil identity", optica applicata, Vol. XXXIV, No. 3, pp (405-418), 2004.
[5] A. Stelmaszewski, "Application of fluorescence in studies of marine petroleum pollutants", Akademia Morska w Gdyni, pp (74-83), 2012.
[6] Ryder A. G., "Analysis of crude petroleum oils using fluorescence spectroscopy", Springer, In: Geddes CD, Lakowicz JR (eds) Annual reviews in fluorescence, London, 2005.
[7] J. Steffens, E. Landulfo, L. C. Courrol and R. Guardani, "Application of fluorescence to the study of crude petroleum", Journal of fluorescence, Vol. 2, No. 3, pp (859-864), 2009.
[8] Igor N. Evdokimov and Alexandr P. Losev, " Potential Of UV-Visible Absorption Spectroscopy For Characterizing Crude Petroleum Oils", Oil and Gas Business, 2007.
[9] S. Goncalves, J. Castillo, A. Ferna ndez and J. Hung "Absorbance and fluorescence spectroscopy on the aggregation behavior of asphaltene - toluene solutions", ELSEVIER, Fuel, No. 83, pp (1823–1828), 2004.
[10] http://www.ucc.ie/academic/chem/dolchem/html/comp/ethanol.html.
[11] Coakley W. A., "Comperhansive identification of oil spills by fluorescence spectroscopy fingerprinting ", proceedings of the oil spill conference, American petroleum institute, Washington, pp (215-222), 1973.
Cite This Article
  • APA Style

    Naseer Mahdi Hadi, Ayad Z. Mohammed, Fareed F. Rasheed, Shahad Imad Younis. (2016). Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil. American Journal of Physics and Applications, 4(3), 78-83. https://doi.org/10.11648/j.ajpa.20160403.12

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    ACS Style

    Naseer Mahdi Hadi; Ayad Z. Mohammed; Fareed F. Rasheed; Shahad Imad Younis. Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil. Am. J. Phys. Appl. 2016, 4(3), 78-83. doi: 10.11648/j.ajpa.20160403.12

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    AMA Style

    Naseer Mahdi Hadi, Ayad Z. Mohammed, Fareed F. Rasheed, Shahad Imad Younis. Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil. Am J Phys Appl. 2016;4(3):78-83. doi: 10.11648/j.ajpa.20160403.12

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  • @article{10.11648/j.ajpa.20160403.12,
      author = {Naseer Mahdi Hadi and Ayad Z. Mohammed and Fareed F. Rasheed and Shahad Imad Younis},
      title = {Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil},
      journal = {American Journal of Physics and Applications},
      volume = {4},
      number = {3},
      pages = {78-83},
      doi = {10.11648/j.ajpa.20160403.12},
      url = {https://doi.org/10.11648/j.ajpa.20160403.12},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ajpa.20160403.12},
      abstract = {The fluorescence spectroscopy (FS) is increasingly used in petroleum technology due the availability of better optical detection techniques, because FS offers high sensitivity, good diagnostic potential, and relatively simple instrumentation. Absorption and fluorescence spectrum of crude oil was studied at room temperature using optical path cuvette 1 cm. In this work, the absorption spectra were scanned (190-1100) nm while the emission spectra were obtained at different excitation wavelengths (266, 337, 420, and 488) nm. Crude oil was diluted by absolute ethanol to prepare different concentrations of crude oil. Ethanol as a solvent was used to dilute crude oil to obtain a solution transparent and the light could be transmitted. This work considers as an additional spectroscopic tool to develop into a fast responsive system for charchtrize the crude oil.},
     year = {2016}
    }
    

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    T1  - Determination of Absorption and Fluorescence Spectrum of Iraqi Crude Oil
    AU  - Naseer Mahdi Hadi
    AU  - Ayad Z. Mohammed
    AU  - Fareed F. Rasheed
    AU  - Shahad Imad Younis
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    N1  - https://doi.org/10.11648/j.ajpa.20160403.12
    DO  - 10.11648/j.ajpa.20160403.12
    T2  - American Journal of Physics and Applications
    JF  - American Journal of Physics and Applications
    JO  - American Journal of Physics and Applications
    SP  - 78
    EP  - 83
    PB  - Science Publishing Group
    SN  - 2330-4308
    UR  - https://doi.org/10.11648/j.ajpa.20160403.12
    AB  - The fluorescence spectroscopy (FS) is increasingly used in petroleum technology due the availability of better optical detection techniques, because FS offers high sensitivity, good diagnostic potential, and relatively simple instrumentation. Absorption and fluorescence spectrum of crude oil was studied at room temperature using optical path cuvette 1 cm. In this work, the absorption spectra were scanned (190-1100) nm while the emission spectra were obtained at different excitation wavelengths (266, 337, 420, and 488) nm. Crude oil was diluted by absolute ethanol to prepare different concentrations of crude oil. Ethanol as a solvent was used to dilute crude oil to obtain a solution transparent and the light could be transmitted. This work considers as an additional spectroscopic tool to develop into a fast responsive system for charchtrize the crude oil.
    VL  - 4
    IS  - 3
    ER  - 

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Author Information
  • Ministry of Science and Technology, Materials Research Directorate, Laser & Electro-Optics Research Center, Baghdad, Iraq

  • Laser & Optoelectronics Engineering Department, University of Technology, Baghdad, Iraq

  • Laser & Optoelectronics Engineering Department, University of Technology, Baghdad, Iraq

  • Laser & Optoelectronics Engineering Department, University of Technology, Baghdad, Iraq

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